2025-06-30
【學術亮點】銀奈米粒子改質作為陰極催化劑增強陰離子交換膜燃料電池
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【學術亮點】銀奈米粒子改質作為陰極催化劑增強陰離子交換膜燃料電池
Intelligent Husbandry: AI Green Energy Management and Circular Use of Sensing Platform【Graduate Institute of Precision Engineering /Hsiharng Yang / Professor】
智慧農牧場：AI綠能管理與循環利用之感測平台【精密所楊錫杭教授】
上架日期：2025/06/03
Intelligent Husbandry: AI Green Energy Management and Circular Use of Sensing Platform【Graduate Institute of Precision Engineering /Hsiharng Yang / Professor】
智慧農牧場：AI綠能管理與循環利用之感測平台【精密所楊錫杭教授】
| 論文篇名 | 英文：Silver Nano-particles Modification Used as Cathode Catalysts to Enhance Anion Exchange Membrane Fuel Cells 中文：銀奈米粒子改質作為陰極催化劑增強陰離子交換膜燃料電池 |
| 期刊名稱 | Electrochimica Acta |
| 發表年份, 卷數, 起迄頁數 | 2025, 534, 146544 |
| 作者 | Fa-Cheng Su, Guan-Yu Chu , Hsiharng Yang(楊錫杭)∗ |
| DOI | 10.1016/j.electacta.2025.146544 |
| 中文摘要 | 本研究主要探討使用非貴金屬催化劑作為陰極電極，以提升陰離子交換膜燃料電池（AEMFC）性能。因為銀奈米粒子具有優異的氧還原反應（ORR）特性且相較於鉑（Pt）成本更低，因此它們是AEMFC陰極電極的良好候選材料。有兩種方法可以實現以Ag取代Pt的目標。第一種是使用銀奈米粒子製程，其所得電池性能與Pt相近，差距為3.5%。另一種是使用硝酸鋯修飾Ag表面以提升電池性能。在實驗中，使用酸洗的Vulcan XC72R炭黑以增加其表面的官能基，這也可以增加銀奈米粒子與陰極基材的結合。硝酸銀經由化學過程被還原為銀奈米粒子以用於陰極。結合還原劑硝酸銨鋯與管式爐退火過程中的氮氣環境，完成了含40 wt %銀奈米粒子的陰極催化劑。鉑（Pt/C）（40 wt %）與異丙醇（IPA）和去離子水（DI）按一定比例混合後用於陽極。實驗發現，陽極Pt/C與IPA、DI的混合比例為7:3，陰極Ag/C與IPA、DI的混合比例為5:5。透過此研究，發現最高的電池性能達到623 mW/cm²。本研究可實現將非貴金屬催化劑銀奈米粒子用作AEMFC的陰極。 |
| 英文摘要 | This research mainly explores the non-precious metal catalyst used as in the cathode electrode to improve the anion exchange membrane fuel cell (AEMFC) performance. Because nano-silver particles with excellent oxygen reduction reaction (ORR) characteristics and lower cost compared to Pt, they are good candidates for cathode electrode in AEMFC. Two approaches can realize the target to use Ag instead of Pt. It was implemented with processing Ag nano-particle, the resulted cell performance close to Pt with 3.5 % difference. The other one is to modify Ag surface using cerium nitrate to enhance cell performance. In the experiment, the pickling Vulcan XC72R carbon black was used to increase functional group of Vulcan XC72R carbon black attached on their surface. It also can increase Ag nano-particles to integrate with the cathode substrate. The silver nitrate was reduced to Ag nano-particles through a chemical process for the cathode. Combined with the reducing agent ammonium cerium nitrate and the N2 gas environment during the annealing of the furnace tube, the cathode catalyst with 40 wt % Ag nano-particles were completed. While platinum (Pt/C) (40 wt %) was mixed with isopropanol (IPA) and deionized water (DI) with a certain ratio for the anode. It was found to be 7:3 (IPA, DI) mixed with Pt/C for the anode and then 5:5 (IPA: DI) mixed Ag/C for the cathode. Through this study, it was found that the highest cell performance reached 623 mW/cm2. It can implement non-precious metal catalyst, Ag nano-particles, to be used as cathode for AEMFC. |
| 發表成果與AI計畫研究主題相關性 | 此研究開發新型陰極催化劑增強燃料電池性能，搭配子九計畫導入CNN模型以預測用電趨勢，結合畜牧場環境數據與AI技術，建構智慧農業能源管理模式，達到節電、省電、減碳等目標，並在此研究基礎上發展更加有效率發電方式。 |
